Glad you're interested in Sins modding. While it's far from a complete resource, the sins modding wiki might be able to help you with basic questions. Otherwise the community is pretty good at answering questions (provided we actually know the answers of course).
As for modeling, you should be able to do everything you need with freeware. I think Sins meshes use the .xsi format, so you'll need to find a 3d modeling program that can support it (you might need plug-ins). The documentation with the forge tools in the download section has some more detailed information about this, but keep in mind the reference data is out of date.