I dont know what you mean.... exactly.
But if you cant remember whos your friend or foe, try to use some ingame content
Options -> User Interface -> Show Team colors.
And there you are, your empire color will be green, your friends yellow und your enemys red.
On the left side of your screen there is the Empire Window where you can see your full empire. And if an other ship is in one of your Systems, you can see it there as a little square point with a different color.
You can select the ships there and you dont have to chase them in the 3d view.
Ironclad did a great job with that feature,
but i still think blue would be better for friends... yellow feels like they arent friendly at all.